| PROCEEDINGS OF THE 7th INTERNATIONAL MEETING ON RECENT ADVANCES IN MR APPLICATIONS TO POROUS MEDIA MRPM7 |
| Ecole Polytechnique, Palaiseau, France 4-8 July 2004 |
| A special issue of: Magnetic Resonance Imaging |
| Edited by: Paola Fantazzini John C. Gore Jean-Pierre Korb |
| The Meeting was
organized with the further support of : |
| Schlumberger-Doll Research,
Ridgefield, Connecticut, USA. Bruker Biospin S.A., Wissembourg, France STELAR s.r.l., Mede (PV), Italy Università di Bologna, Bologna, Italy Varian Inc., France ATILH Association Technique de l’Industrie des Liants Hydrauliques, La Défense, France Resonance Instruments Ltd, UK IFP, Rueil Malmaison, France RS2D, Strasbourg, France |
| SCIENTIFIC ADVISORY COMMITTEE | ORGANISING COMMITTEE |
| Jean-Pierre Korb
(Chair, F) Jerzy Blicharski (PL) Bernhard Blümich (D) Richard Bowtell (GB) Robert J.S. Brown (USA) Paul Callaghan (NZ) Paola Fantazzini (I) Eiichi Fukushima (USA) Lynn Gladden (GB) John Gore (USA) Laurie Hall (GB) Martin Hürlimann (USA) Jörg Kärger (D) Rainer Kimmich (D) Igor Koptyug (RU) Peter McDonald (GB) Sir Peter Mansfield - Nobel Prize 2003 (GB) Bruno Maraviglia (I) Ken Packer (GB) Pabitra Sen (USA) John Strange (GB) Hans Thomann (USA) Rustem Valiullin (RU) Marija Vilfan (SI) |
Jean-Pierre Korb (Chair, Ecole Polytechnique, Palaiseau) Pierre Levitz (Ecole Polytechnique, Palaiseau) Dominique Petit (Ecole Polytechnique, Palaiseau) Fabien Barberon (Ecole Polytechnique, Palaiseau) Cecile Vigouroux (Ecole Polytechnique, Palaiseau) Geneviève Guillot (Université d'Orsay) Hélène Zanni (ESPCI, Paris) Jacques Leblond (ESPCI, Paris) Michel Rochet (Collège de Polytechnique) Denise Abboud (Collège de Polytechnique) Émilie Duley (Collège de Polytechnique) |
| The
Conference was divided into 13 Sessions. The Chairs were as follows: Session I: J. H. Strange Session II: M. Goldman Session III: P. Levitz Session IV: P.T. Callaghan Session V: S. Vasenkov Session VI: R. G. Bryant Session VII: G. Guillot Session VIII: B. Blümich Session IX: M. Fleury Session X: H. Zanni Session XI: S. Stapf Session XII: P. J. McDonald Session XIII: R. Kimmich |
| CONTENTS |
|
EDITORIAL The Seventh International Conference on Magnetic Resonance Applications to Porous Media Paola Fantazzini, John C. Gore and Jean-Pierre Korb INVITED LECTURES Memorial lecture honoring Giulio Cesare Borgia Magnetic Resonance for fluids in Porous Media at the University of Bologna Paola Fantazzini Some perspectives on dispersion and the use of ensemble-averaged PGSE NMR P. T. Callaghan Long-range diffusion in beds of nanoporous particles: Pitfalls and Potentials S. Vasenkov and J. Kärger Confined dynamics, forms and transitions in colloidal systems: From clays to DNA P. E. Levitz Hyperpolarization of 13C through order transfer from para-hydrogen: a new contrast agent for MRI M. Goldman, H. Jóhannesson, O. Axelsson and M.Karlsson Viscoelastic shear properties of in-vivo breast lesion measured by MR-elastography R. Sinkus, M. Tanter, T. Xydeas, S. Catheline, J. Bercoff and M. Fink Nuclear Magnetic Resonance and spin relaxation in biological systems R.G. Bryant and J-P.Korb Field-cycled PEDRI imaging of free radicals with detection at 450 mT D.J. Lurie, G.R. Davies, M.A. Foster and J.M.S. Hutchinson PEDRI imaging of free radical distribution in environmental science applications – first results and perspectives N. Nestle, K. Shet and D. Lurie Polymer chain dynamics under nanoscopic confinements R. Kimmich, N. Fatkullin, C. Mattea and E. Fischer Advances of unilateral, mobile NMR in nondestructive materials testing B. Blümich, F. Casanova, J. Perlo, S. Anferova, V. Anferov, K. Kremer, N. Goga, K. Kupferschläger and M. Adams CONTRIBUTED PAPERS Study of gas-fluidization dynamics with laser-polarised 129Xe R. Wang, M.S. Rosen, D. Candela, R.W. Mair and R.L. Walsworth Concentration-dependent self-diffusion of adsorbates in mesoporous materials R. Valiullin, P. Kortunov, J. Kärger and V. Timoshenko Modelling diffusion in white matter in the brain: a composite porous medium P. N. Sen and P. J. Basser Functional MRI and NMR spectroscopy of an operating gas-liquid-solid catalytic reactor I.V. Koptyug, A.A. Lysova, A.V. Kulikov, V.A. Kirillov, V.N. Parmon and R.Z. Sagdeev Combining macroscopic and microscopic diffusion studies in zeolites using NMR techniques K. Banas, F. Brandani, D. Ruthven, F. Stallmach and J. Kärger PFG NMR study of transport properties of FCC catalysts P. Kortunov, S. Vasenkov, J. Kärger, M. Fé Elía, M. Perez, E. Hansen, M. Stöcker, G.K. Papadopoulous, D. Theodorou, B. Drescher, G. McElhiney, B. Bernauer, V.Krystl, M. Kocirik, A. Zikanova, H. Jirglova, C. Berger, R. Gläser, J. Weittkamp and E.W. Hansen Contrast-enhanced dynamic MRI protocol with improved spatial and time resolution for in vivo microimaging of the mouse with a 1.5 T body scanner and a superconducting surface coil J-C. Ginefri, M. Poirier-Quinot, P. Robert and L. Darrasse DTI of trabecular bone marrow C. Rossi, S. Capuani, F. Fasano, M. Alesiani and B. Maraviglia Morphology and chain dynamics during collapse transition of PNIPAM gels studied by combined imaging, relaxometry and 129Xe spectroscopy techniques S. Kariyo, M. Küppers, M.V. Badiger, A. Prabhakar, B. Jagadeesh, S. Stapf and B. Blümich Water content distribution in a polymer electrolyte membrane for advanced fuel cell system with liquid water supply S. Tsushima, K. Teranishi, K. Nishida and S. Hirai Two dimensional NMR Petrophysics B. Sun and K-J. Dunn Centric scan SPRITE for spin density imaging of short relaxation time porous materials Q. Chen, M. Halse and B.J. Balcom Interactions between chloride and cement-paste materials F. Barberon, V. Baroghel-Bouny, H. Zanni, B. Bresson, J-B. D’Espinose de la Caillerie, L. Malosse and Z. Gan Salt crystallization as damage mechanism in porous building materials - an NMR study L.A. Rijniers, L. Pel, H.P. Huinink and K. Kopinga The influence of superplasticizers on the first steps of tri-calcium silicate hydration studied by NMR techniques I. Pirazzoli, M. Alesiani, S. Capuani, B. Maraviglia, R. Giorgi, F. Ridi and P. Baglioni NMR study of the vapor phase contribution to diffusion in partially filled silica glasses with nanometer and micrometer pores I. Ardelean, G. Farrher, C. Mattea and R. Kimmich Hydrodynamics in two-phase flow within porous media L.D. Anadon, M.H.M. Lim, A.J. Sederman and L.F. Gladden NMR in rotating magnetic fields: Magic angle field spinning D. Sakellariou, C. Meriles, R.W. Martin and A. Pines Multiple modulation multiple echoes: a one-shot method Y-Q. Song Fixed and pulsed gradient diffusion methods in low field core analysis G. Leu, E.J. Fordham, M.D. Hürlimann and P. Frulla A MRI-SPI and NMR relaxation study of drying-hydration coupling effect on microstructure of cement-based materials at early age P. Faure, S. Care, C. Po, and S. Rodts SHORT COMMUNICATIONS Dissolution of laser-polarised xenon in benzene P. Berthault and H. Desvaux Continuous wave MRI diffusion study of water in bentonite clay A.J. Fagan, N. Nestle and D.J. Lurie NMR investigation of gaseous SF6 confinement into EPDM rubber S. Neutzler, M. Terekhov, D. Hoepfel and L. Oellrich Imaging of water distribution in thermally fractured granite by SPRITE M. Yamaguchi, K. Kobori, K. Suzuki, Y. Ikeda and S. Altobelli Xenon NMR measurements of permeability and tortuosity in reservoir rocks R. Wang, T. Pavlin, M.S. Rosen, R.W. Mair, D.G. Cory and R.L. Walsworth Network images of drainage channels in sea spray icing by MR microscopy T. Ozeki, K. Kose, T. Haishi, S. Nakatsubo and Y. Matsuda Measuring pore connectivity by pulsed field gradient diffusion editing with hydrocarbon gasses M. Flaum, G.J. Hirasaki, C. Flaum and C. Straley MRI as a key tool for understanding and modeling filtration kinetics of fibrous media M.J. Lehmann, E.H. Hardy, J. Meyer and G. Kasper Correlation of porous and functional properties of food materials by NMR relaxometry and multivariate analysis A. Haiduc and J. Van Duynhoven Diffusion of polyethyleeneglycols in casein solutions and gels as studied by pulsed field gradient NMR R. Colsenet, O. Soderman and F. Mariette Displacement propagators of brine flowing within different types of sedimentary rocks D.A. Verganelakis, J. Crawshaw, M.L. Johns, M.D. Mantle, U. Scheven, A.J. Sederman and L.F. Gladden Determination of water compartments in rat myocardium using combined D-T1 and T1-T2 experiments J.G. Seland, M. Bruvod, H. Anthonsen, H. Brurok, W. Nordhøy, P. Jynge and J. Krane A comparison of experimental and simulated propagators in porous media using Confocal Laser Scanning Microscopy, lattice Boltzmann hydrodynamics simulations and Nuclear Magnetic Resonance R.J. Harris, A.J. Sederman, M.D. Mantle, J.Crawshaw and M.L. Johns Magnetic resonance imaging and relaxation analysis to predict non-invasively and non-destructively salt-to-moisture ratios in dry-cured meat P. Fantazzini, V. Bortolotti, C. Garavaglia, M. Gombia, S. Riccardi, P. Schembri, R. Virgili and C. Soresi Bordini NMR-propagator measurements in porous media in the presence of surface relaxation and internal fields U.M. Scheven, J.G. Seland and D.G. Cory Quadrupolar interaction study of various cations confined in porous charged polymer films of sPI ionomers A-L. Rollet, P. Porion, A. Delville, O. Diat and G. Gebel MRI-investigation and complementary numerical simulations of flow through random bead packings with low aspect ratio C. Heinen, J. Tillich, H. Buggisch, T. Zeiser and H. Freund Micropore size analysis in oilwell cement by proton nuclear relaxation G. Le Saoût, E. Lécolier, A. Rivereau and H. Zanni Structure characterization of foams and filled polymers by means of MRI N. Eisenreich, A. Geissler, E. Geissler and J. Götz Field-gradient NMR diffusometry in poly(ethylene oxide) melts confined to nanoscopic pores of solid methacrylate matrices E. Fischer, U. Beginn, N. Fatkullin and R. Kimmich Spatial distribution of coke residues in porous catalyst pellets analyzed by field-cycling relaxometry and parameter imaging S. Stapf, X. Ren, E. Talnishnikh and B. Blümich Ultra-fast velocity imaging of single- and two-phase flows in ceramic monolith J. J. Heras, A.J. Serderman and L.F. Gladden Rapid imaging of fluid flow patterns in a narrow packed bed using MRI M.C. Sains, M.S. El-Bachir, A.J. Sederman and L.F. Gladden Determination of porosity and flow distributions in packed beds by magnetic resonance imaging (MRI) N.L. Nguyen, V. Van Buren, R. Reimert and A. Von Garnier, Flow measurements below 50μm: NMR microscopy experiments in lithographic model pore spaces E. Kossel and R. Kimmich ABSTRACT OF A NUMBER OF INVITED LECTURES AND CONTRIBUTED PRESENTATIONS NMR and MRI from nanometers to meters A. Pines Complex molecular dynamics in confinement H.W. Spiess Application of diffusion- relaxation distribution function M.D. Hürliman Non equilibrium phase behavior for oils in porous media H. Thomann Ultrasound stimulated NMR relaxometry: application to the study of molecular dynamics in liquid crystals materials E. Anoardo and F. Bonetto Optimization of resolution in gas MRI R.H. Acosta, L. Agules-Pedros, P. Blümler and H.W. Spiess Analysis of CPMG decay curves for hyperpolarised helium-3 in lungs: susceptibility contrast and lung space geometry G. Guillot, A. Vignaud, L. de Rochefort, X. Maître and E. Durand Combined relaxation and pulsed field gradient MRI to acquire sub-pixel information for molecular displacements of fluids in porous media H. Van As, P.A. de Jager, F. Vergeldt and C. Windt The development of geomagnetic field nuclear magnetic log V. Sapunov, G. Takkand, E. Ligus and T. Khismetov Investigation of large volume cement-based materials J. Boguszynska, P.J. McDonald, J. Mitchell, L. Monteilhet, M. Mulheron and J. Tritt Goc Estimation of length-scales in soils by MRI N.E. Daidzic, S. Altobelli and J.I.D. Alexander ABSTRACT OF POSTERS The CPMG measurement of restricted diffusion in a static gradient L.J. Zielinski and M. D. Hürlimann Correlations between transverse relaxation and internal gradients in porous systems containing oil and water J.G. Seland, K.E. Washburn, H.W. Anthonsen and J. Krane Results on the diffusivity of partly fluorinated hydrocarbons in polymers S. Neutzler and L.R. Oelrich Visualization of benzene diffusion in a zeolite bed using a slice selection procedure S. Leclerc, J. Fraissard and D. Canet Dynamics in ionomer membranes for fuel cell applications J.C. Perrin, S. Lyonnard, P. Levitz, A. Guillermo, O. Diat and G. Gebel High resolution magic angle spinning (hr-MAS) NMR for the characterization of organotins grafted to polymers M. Biesemans, L. Lokeren, K. Poelmans, V. Pinoie, F. Mercier, J. Martins and R. Willem Flow in porous media measured with a single-sided NMR sensor J. Perlo, F. Casanova and B. Blümich Low frequency backbone fluctuations in rotationally constrained proteins J.P. Korb and R.G. Bryant Design and construction of a portable one-sided access NMR probe M.W. Hunter, P.T. Callaghan, R. Dyskra, C.D. Eccles and S. Vamanan MRI study of drainage process in a model porous column: application to modelisation of diphasic drainage P. Faure, J. Benard, R. Eymard and X. Nicolas Single-sided NMR analysis on model systems for the evaluation of in situ measurements on cultural heritage materials C. Casieri, F. De Luca and P. Fantazzini NMR relaxation and 13C CPMAS applied to wood characterization M. Alesiani, F. Proietti, S. Capuani, M Fioravanti, M. Paci and B. Maraviglia Velocity distributions remotelly measured with a single-sided NMR sensor F. Casanova. J. Perlo, and B. Blümich Surface and confinement induced molecular dynamics of thin lipid film: a 1H multiple-quantum NMR study B. Jagadeesh, A. Prabhakar, A. Buda, D.E. Demco and B. Blümich Sedimentary rocks characterization with a single-sided NMR instrument G. Maddinelli and E. Peron Application of 29Si homonuclear and 1H/29Si heteronuclear NMR correlation to structural studies of calcium silicate hydrates F. Brunet, Ph. Bertani, Th. Charpentier, A. Nonat and J. Virlet Feasibility study of a mobile NMR scanner for porosity measurements on deep sea ocean drilling core samples B. Blümich, S. Anferova, J. Arnold, R. Pechnig, R. Fechete and C. Clauser Relations between gas diffusion and morphology in macroporous systems C. Vigouroux, D. Petit and P. Levitz Non-invasive monitoring of water intake in porous rocks P. Prado and J. Asmus Restricted diffusion simulations in porous media for nuclear magnetic resonance (NMR) applications A. Valfouskaya, M. Fleury, J.F. Thovert and P.M. Adler Surface nuclear magnetic resonance – Applications in hydrogeophysics and future developments M. Müller and Y. Yaramanci Computer modeling of pore structure using petrographic and NMR data R. Kadushnikov, V. Neshchadimov, V. Khvatkov and V. Sapunov NMR multi-quantum coherence and relaxometry investigations of the ordering effects of cylindrical pore walls on monolayer and multilayer adsorbed 5CB liquid crystals J. Bharatam, S. Stapf and B. Blümich Field-dependence of relaxation time distribution in rock samples V. Bortolotti, R.J.S. Brown, P. Fantazzini, G. Ferrante and S. Sykora Moisture measurements of porous products B. Blümich, O. Dicoi and M. Krüger Microscopic distribution of internal magnetic fields for partially saturated Berea sandstone and its application to the study of pore filling processes Q. Chen, A.E. Marble, B.G. Colpitts, and B.J. Balcom A magnetic resonance imaging study of temperature and water distribution during microwave processes K. Knoezer, M. Regier, E.H. Hardy, A. Hermann and H. Schubert MRI study of anomalous moisture diffusion in an expoxy adhesive G. LaPlante, A.V. Ouriadov, Q. Chen, P. Lee-Sullivan and B.J. Balcom Porous structure of treated rice grain by MRI abnd PGSE A. Mohoric, J. Van Duynhoven, F. Vergeltdt, E. Gerkema, A de Jager and H. Van As MRI of structure and convection in solidifying porous mushy layers A.J. Sederman, P. Aussillous, H.E. Huppert, M.G. Worster and L.F. Gladden Derivation of NMR response to permeability correlations from Xray-CT images C.H. Arns, M.A. Knackstedt, M. Hunter and P. Callaghan Significance of NMR-derived pore size using the grain and pore throat model G. Chauveteau and M. Fleury Magnetic resonance visualisation of flow in model fixed bed reactors with low aspect ratio X. Ren, S. Stapf and B. Blümich Hydration and setting of plaster materials J. P. Korb, H. Jaffel, V. Morin and S. Boivin Investigation of porosity and structure during the compression of fine particulate sediments A. Erk, E.H. Hardy and W. Stahl MRI measurement of water content in a polymer electrolyte membrane for investigation of membrane thickness effect on fuel cell performance K. Teranishi, S. Tsushima and S. Hirai Monitoring of mesoporous material inner pore surface morphology by multinuclear NMR I.G. Shenderovich, D. Andreeva, G. Buntkowsky and H.H. Limbach 23Na and 35Cl transport in porous building materials as studied by NMR J.H.R. Feijen, L.A. Rijniers, H.P. Huinink, L. Pel and K. Kopinga Simulation of edge enhancement profile evolution in PGSE of spins in 1D pore A. Duh and A. Mohoric Systematic MRI investigations of stone conservation treatments with traditional and innovative hydrophobic products M. Camaiti, V. Bortolotti, M. Gombia and P. Fantazzini Sterically hindered bases as a probe molecules for surface structure analysis of mesoporous materials D.V. Andreeva, I.G. Shenderovich, G. Buntkowsky and H.H. Limbach Non-quadratic dependence of 1/T2 on echo spacing with pore-scale inhomogeneous fields in porous media P. Fantazzini and R.J.S. Brown Modulated gradient spin echo for probing molecular dynamics in porous media I. Serša, A. Mohorič, J. Stepišnik Multi-nuclei NMR (11B, 129Xe) studies on behavior of organic eletrolyte at charged and discharged states on activated carbon as an electrode for EDLC K. Saito, K. Kanehashi, S.I. Lee, M. Satoshi and I. Mochida A NMR study of the adsorption-desorption kinetics of dissolved tetraalanine in MCM-41 mesoporous material S. Pizzanelli, S. Kababya, V. Frydman, M. Landau and S. Vega The study of nanopores in coal using Xe and hyperpolarized Xe NMR spectroscopy K. Saito, K. Kanehashi, A. Kimura and H. Fujiwara Proposal of a flow induced relaxation mechanism in porous media H. Tiraboschi, C. Mattea and R. Kimmich Isotrope/Nematic transition within aqueous dispersions of charged anisotropic colloids detected by 23Na nuclear magnetic resonance spectroscopy and 1H PGSE-NMR measurements P. Porion, M. Al-Mukhtar, A.M. Faugere and A. Delville Critical evaluation of reverse-flow testing of chromatography columns D.J. Holland, A.P.J. Middelberg, L.F. Gladden and B. Akpa Mobile NMR equipment for measurements of the pore size distributions of deep sea ocean drilling core samples V. Anferov, S. Anferova, B. Blümich and P. Blümler Spin-lattice relaxation of fluorinated gases in pores A.F. McDowell and D. Kuethe NMR acceleration mapping in fluid filled correlated percolation model objects B. Buhai, A. Kühnle, M. Weber and R. Kimmich Two-phase fast exchange dynamics in partially porous glasses studied by field-cycling NMR relaxometry C. Mattea, I. Ardelean, E. Anoardo, S. Wonorahardjo and R. Kimmich Nondestructive testing of PE pipes for gas and water transport K. Kremer, B. Blümich, F. Casanova and J. Perlo The freezing and melting phenomena in mesoporous materials as studied by 129Xe NMR V. Telkki, J. Lounila and J. Jokisaari Pore-size distribution measurement by the effect of internal magnetic field with spatial resolution by centric scan SPRITE MRI Q. Chen, J. Rioux, Z. Zhang and B.J. Balcom Electric current density mapping of porous model objects. NMR microscopy experiments and numerical simulations B. Buhai and R. Kimmich Grain and inter-grain porosity quantified in unconsolidated porous media by NMR relaxation P. Fantazzini, V. Bortolotti, R.J.S. Brown, M. Gorbia and N.E. Daidzic Probing the textural structure of mesoporous matrices by the slow dynamics of highly confined liquid crystals J.P. Korb, P. Levitz, N. Léon and I. Bonalde Different techniques to quantify pore-space lengths in porous rocks and artificial porous media P. Fantazzini, A. Tucci and R. Viola Topological criteria based thresholding technique of high-resolution magnetic resonance microscopy of mouse bone: a preliminary reproducibility evaluation L. Pothuaud, S. Miraux, G. Raffard, J. M. Franconi and J. Amédée Fracture and matrix porosity quantified in reservoir rocks by three-dimensional MRI image and relaxation time map analysis V. Bortolotti, P. Fantazzini and M. Gombia Baseline problems for some modulus-recorded CPMG T2 data P. Fantazzini and R.J.S. Brown Unsuspected radiofrequency heating of solid samples during Dynamic MAS NMR experiments J.B. d’Espinose de Lacaillerie, N. Barros, N. Champavert and D. Reichert Field-cycling NMR relaxometry of water in reversed micelles G. Kassab, J.P. Korb and P. Levitz A portable NMR system for remote measurements R. Dykstra, P.T. Callaghan, C.D. Eccles and M.W. Hunter NMR study of the vapor phase contribution to diffusion in partially filled silica glasses with nanometer and micrometer pores I. Ardelean, G. Farrher, C. Mattea and R. Kimmich NMR restricted diffusion experiments in porous media and emulsions M. Fleury and F. Deflandre The phase, structure and dynamics of water/ice at an SBA silica surface J.B.W. Webber, J.H. Strange and J.C. Dore Water in wood cell wall below fibre saturation L.G. Thygesen, S.B. Engelsen and P. Hoffmeyer Probing water molecules in cement blends usin 1H nuclear magnetic resonance relaxometry J.Ph. Gorce, N.B. Milestone and S. Farris Flow dynamics of fluid in a porous structure by NMR: GPA method J. Stepisnik Molecular structures and dynamics of water confined in fabricated one-hundred-nanometer-sized channels T. Tsukahara, A. Hibara and T. Kitamori Magnetic resonance imaging of in-situ saturation in porous media for CO2 geologic sequestration T. Suekane, T. Ishii, S. Tsushima and S. Hirai Phase transitions and dynamical properties of aromatic liquids confined in MCM-41 and SBA-15 G. Dosseh, C. Lequellec, N. Brodie, P. Levitz and C. Alba-Simionesco 2D exchange spectroscopy and 2D time domain NMR of water in MCM41 J. Liang, J. Hassan, C. Lemaire, R. Holly, and H. Peemoeller Surface induced order and dynamic heterogeneity in ultra thin polymer films: 1H MQ NMR and spin-spin relaxation studies B. Jagadeesh, F. Casanova, J. Perlo, D.E. Demco and B. Blümich |